This was a topic of discussion on HH's last year at this time. I contacted True Vue then and this was the response that was given regarding the breakdown of the coating on their conservation quality glass.
This is reprinted with permission from Patti Dumbaugh (originally posted 3/1/01):
Hard coatings for glass can be divided into two major categories:
Inorganic, (essentially bound-silica), and organic (polymeric). The hard
coating provided by Tru-Vue to its customers is primarily an inorganic
silica-based film containing a small percentage of additional organic
components.
Hello, Hitchhikers:
Over the past few months there have been a lot of calls into Tru Vue and
also discussion on the hitchhiker about how long various UV coatings last
and what difference organic vs. inorganic means in terms of longevity. I
received requests for more scientific information. The response below is
from the scientists at Gentek - I'm sure you've all heard of this company -
they are a leader in research & development of many innovative products.
It's as much as I can share without revealing all of our proprietary
technology, but I hope that for those of you who are really interested in
the chemistry of the coating, this will answer your questions.
'This film consists of inert silicas chemically bound directly to the silica
in the glass surface, via Si-O-Si bonds, the same bonds that hold the glass
itself together. The inert nature of this siliceous coating means it is
non-reactive, non-volatile, permanently hard, and nearly as resistant to
weathering, humidity, temperature extremes, chemicals and other
environmental factors as the raw glass surface itself. Thus, the coating is
engineered for permanence from the start.
Tru-Vue's coated glass far outperforms the popular organic-based (typically
acrylic) glass coatings in ASTM accelerated testing such as humidity
resistance and salt fog. And while these polymeric coatings sometimes
contain silica as an additive in an attempt to compensate for poor scratch
resistance, it does not change the underlying physical weaknesses of
polymeric-based coatings. Indeed, Tru-Vue's coating is significantly
superior to these organic coatings in chemical resistance, water
sensitivity, long-term adhesion, and hardness.
The organic component of Tru-Vue's coating consists of a small percentage of
ultra-violet (UV) light absorbers that allow the film to function as a
filter for damaging UV light. What is particularly unique about the patented
UV absorbing system built into Tru-Vue's coating versus other similar
coatings, is the permanence of the absorber. The UV absorber is chemically
bound to the rest of the coating during the production process, to yield an
absorber that does not degrade, migrate, or extrude to the surface (common
problems with some coatings). The only way to physically damage the UV
absorber in Tru-Vue's coating is to expose it continuously to extremely high
temperatures, in excess of 400 degrees F, which is not a likely circumstance
under any conceivable conditions of end use.
Many polymeric coatings, on the other hand, such as poly methyl
methacrylates, polyethylenes, and aliphatic polyesters, are susceptible to
degradation when exposed to UV light due to the presence of chromophoric
impurities that absorb in the UV region. This eventually leads to photo
degradation of the film. Thus, these polymeric coatings require the presence
of UV absorbers for the purpose of self-protection, as much as for their
ultimate UV filtering function.'
Patrica L. Dumbaugh
Director of Marketing
Tru Vue
pdumbaugh@tru-vue.com