And yet ironically, Sintra is extensively used as a photo mounting substrate.
You do not say what the intended use of the photographs is, but if they are for display or commercial purposes, Sintra my be perfectly appropriate.
You also called them, "photos" but what are they really? Are they printed on resin coated photographic paper? Are they inkjet prints? Solvent based or water soluble ink? I ask this because each will pose its own set of limitations on the adhesive you use, the handling and cleanup.
Our experience is that Sintra is best used with roller mounting machines and film adhesives. If the edges are important, it is also best cut on a saw. (Or precut slightly undersized and then the photo is trimmed around the board after mounting to get the cleanest edge. We usually do this for 4-6mm board.)
Are the photos being framed? If so, then why use Sintra? If not, the edges are probably an important consideration, but then 1/8" is pretty flimsy stuff.
Also remember that the surface of Sintra is very unforgiving so be sure it is very clean (and also the backs of the photos.) I recommend the use of a drs roller dust removal tool distributed by Dry-Tac. All shops should have one for preparation of all mounting substrates.
http://drytac.com/productcart/pc/viewCat_P.asp?idCategory=16
If you use Vaccumount, remember that you need to allow the solvent to evaporate. This means a 6 minute open time per piece, which also means that unless your environment if very clean, debris can land on the back of the print while you are waiting for the glue to dry. Also, overspray can be a challenge if you get some on the face of the piece. With RC photos, naptha with take it right off. With inkjet prints, naptha will also take off the surface of the print!
If you have never worked with Sintra (or PVC) as a backing, I am not sure that I would ramp up my learning curve on customer's goods. Can they also furnish test prints/paper?
Sintra is also expensive to use on a "trial/experimentaion/test" basis. Our plastics supplier often has damaged sheets with cracks in the middle or broken corners that can be purchased at a discount. (You may even find some off colors that are damaged that you can experiment with.) Our supplier also sells cut offs from jobs priced "per pound" that would be suitable to try cutting and mounting on.
My biggest concern for you is not that you can get the photos onto the board, but that they will stay there and not come flying back a few weeks/months later with curled edges or bubbles. Mounting paper to foam core is one thing, mounting two pieces of plastic (rc photos and Sintra (pvc)) and getting them to stay attached (especially if the edges are not covered by a frame) is another.