Not sure John, we paint our convex glass, with never a problem with what would be either side of float to inner convex side.
Could be either way, after cleaning, cutting, setting up in the kiln etc, then spraying the inner surface.
At the moment, we spray with 2k auto clear (with additives to block UV, and also glass adhesion promoter).
This is made from float, and tin side may even help with adhesion. (something to 'key' to ?)
There were 2 recent threads about painting cc on coated side, maybe there are some tips in one of these ?
http://www.thegrumble.com/showthread.php?t=28295
http://www.thegrumble.com/showthread.php?t=29061
For a fairly easy way to do this, I would :
Use small touch up spray packs (acrylic lacquer) available from auto parts shops.
Remember float will make the colour quite a bit greener so get something lighter and redder looking on the cap. A perfect colour match will be difficult, unless trialled.
Clean glass normally.
Mask up as needed, quality masking tape and double newspaper to stop bleed, you can get 'fine line' tape from auto parts / paint supplier that leaves a finer edge if you like, but should be ok as long as you don't apply 1/16" of paint !
Use a wax & grease remover from auto shop too (usually avail in 1lt here, but you may have qrt). Don't need much.
(Wipe on, wipe off)
After this evaps a bit, final wipe with clean dry cloth.
Then, with tack off time between . . .
Very light first coat.
Another light coat.
Maybe a medium coat.
Spray in flat format, much larger brown paper etc on bench, glass flat on this so no overspray on other side, good ventilation, and it may look wishy washy in cover when finished and held up to light, but will look more opaque and be ok in the frame with something behind it.
Don't go too thick on the paint, you don't want a big paint edge on the masking tape.
Remove the tape while still slightly tacky, but tacked off a bit, pul off at 45o angle away from the paint edge.
Still, this is no quick and easy job, you have to go to the auto store, and something like this may take a couple of hours total.