The appropriate glue for plastics has been debated here for years. My choice is that yellow glue used for black drain pipes - the plumbers stuff. $5 a can. Perfect for the application. I've used it on hundreds if not over a thousand frames in the past ten years.
Apply it with that fuzzy ball on the end of the metal rod. Keep the glue at least 1/8th of an inch away from the top edge, or it will squeeze out and destroy the finish. I apply it only on one face, and only on one corner at a time. Apply a thin coat.
V-nail away from the outside corner - start at least 1/2 inch away from the outer corner. Only once have I had a frame crack - the molding was stored outside below freezing, and it was too brittle.
Practise on some offcuts - glue a joint, wait ten minutes, then break it. The broken corner will be really ugly - the plastic stays glued, and the glued part comes away from the molding.
The manufacturer I buy it from sells to the big framing factories in Toronto - the ones that supply hotels, big boxes and starving artists selling sofa sizes. They mix a glue concoction of acetone and the powder that goes into the manufacturing of the moldings. They don't waste their time buying pipe glue.
If you have any questions, PM me and I'll send you my phone number. I can tell you more about plastics based on making every mistake in the book with the stuff. I've also made a lot of money with it.